Following Real Madrid's opening day clash against Osasuna, Alonso's men will face off with Real Oviedo and Mallorca to close out August. Just over a month into the 2025–26 campaign, Los Blancos will clash with Atlético Madrid at the Metropolitano. Real Madrid will host the second Madrid derby in March.

La Liga released the fixtures for the 2025-26 season, which will see Barcelona defend the title they won in the previous campaign. They are expected to be competing against Real Madrid

La Liga's fixture list for the upcoming season confirms Barcelona will play their first three matches of the league season away from home.