Donald Trump says Venezuela's embattled opposition leader must be protected, as President Nicolas Maduro prepares to take the oath again after allegedly stealing an election.

Venezuela opposition leader Maria Corina Machado was detained at a march in Caracas on Thursday in her first public appearance in months and her ally, former presidential candidate Edmundo Gonzalez, demanded she be freed immediately.

Maria Corina Machado, a 57-year-old engineer with rock-star appeal, became the fearless figurehead of Venezuela's opposition after being barred from challenging strongman Nicolas Maduro in elections last July.